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Poly[bis-(?(2)-pyrazine-2-carboxyl-ato)-?N,O:O';?N,O:O-cadmium(II)].

ABSTRACT: In the structure of the title compound, [Cd(C(5)H(3)N(2)O(2))(2)](n), the Cd(II) ion is six-coordinated by two N atoms and four O atoms from three different pyrazine-2-carboxyl-ate ligands. One N atom and one O atom of the carboxyl-ate group in the ligand coordinate to the metal center, forming a five-membered chelate ring. The carboxyl-ate anion adopts two types of bridging modes, viz. ?(2)-O and syn-anti. Two Cd(II) ions form a centrosymmetric dimer via a ?(2)-O bridge, and the dimers are linked through the syn-anti carboxyl-ate functional group, forming a two-dimensional polymeric structure extending along (100).

SUBMITTER: Liu G

PROVIDER: S-EPMC2980228 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Poly[bis-(μ(2)-pyrazine-2-carboxyl-ato)-κN,O:O';κN,O:O-cadmium(II)].

Liu Ge G

Acta crystallographica. Section E, Structure reports online 20091224 Pt 1

In the structure of the title compound, [Cd(C(5)H(3)N(2)O(2))(2)](n), the Cd(II) ion is six-coordinated by two N atoms and four O atoms from three different pyrazine-2-carboxyl-ate ligands. One N atom and one O atom of the carboxyl-ate group in the ligand coordinate to the metal center, forming a five-membered chelate ring. The carboxyl-ate anion adopts two types of bridging modes, viz. μ(2)-O and syn-anti. Two Cd(II) ions form a centrosymmetric dimer via a μ(2)-O bridge, and the dimers are link ...[more]

PMID: 21579983

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