Ontology highlight
ABSTRACT:
SUBMITTER: Goto K
PROVIDER: S-EPMC2980245 | biostudies-literature | 2009 Dec
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20091204 Pt 1
The title compound, C(23)H(25)NSi, has an eight-membered silicon-containing heterocyclic ring with an intra-molecular N⋯Si close contact, the transannular distance of which is 2.6294 (18) Å. The resulting geometry about the Si atom is distorted trigonal-bypyramidal, with the N and H atoms occupying apical sites. The dihedral angle between the aromatic rings fused to the eight-membered ring is 63.27 (7)°. ...[more]