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6-(1-Methyl-ethyl)-12-phenyl-5,6,7,12-tetra-hydro-dibenz[c,f][1,5]aza-silocine.


ABSTRACT: The title compound, C(23)H(25)NSi, has an eight-membered silicon-containing heterocyclic ring with an intra-molecular N?Si close contact, the transannular distance of which is 2.6294?(18)?Å. The resulting geometry about the Si atom is distorted trigonal-bypyramidal, with the N and H atoms occupying apical sites. The dihedral angle between the aromatic rings fused to the eight-membered ring is 63.27?(7)°.

SUBMITTER: Goto K 

PROVIDER: S-EPMC2980245 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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6-(1-Methyl-ethyl)-12-phenyl-5,6,7,12-tetra-hydro-dibenz[c,f][1,5]aza-silocine.

Goto Kei K   Fukushima Akihiro A   Kawashima Takayuki T  

Acta crystallographica. Section E, Structure reports online 20091204 Pt 1


The title compound, C(23)H(25)NSi, has an eight-membered silicon-containing heterocyclic ring with an intra-molecular N⋯Si close contact, the transannular distance of which is 2.6294 (18) Å. The resulting geometry about the Si atom is distorted trigonal-bypyramidal, with the N and H atoms occupying apical sites. The dihedral angle between the aromatic rings fused to the eight-membered ring is 63.27 (7)°. ...[more]

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