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2,5-Dichloro-N-cyclo-hexyl-benzene-sulfonamide.


ABSTRACT: The structure of the title sulfonamide, C(12)H(15)Cl(2)NO(2)S, features a distorted tetra-hedral geometry for the S atom [maximum deviation: O-S-O = 120.23?(14)°]. One of the sulfonamide O atoms is coplanar with the benzene ring [C-C-S-O torsion angle = -174.5?(2)°], whereas the other lies well above the plane [C-C-S-O = 57.0?(3)°]. A chair conformation is found for the cyclo-hexyl ring. In the crystal, supra-molecular chains aligned along the c axis are formed via N-H?O hydrogen bonds; these are consolidated in the three-dimensional packing by C-H?O contacts involving the second sulfonamide O atom.

SUBMITTER: Khan IU 

PROVIDER: S-EPMC2983123 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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2,5-Dichloro-N-cyclo-hexyl-benzene-sulfonamide.

Khan Islam Ullah IU   Sharif Shahzad S   Batool Shumaila S   Mumtaz Ahmad Mahmood AM   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20100925 Pt 10


The structure of the title sulfonamide, C(12)H(15)Cl(2)NO(2)S, features a distorted tetra-hedral geometry for the S atom [maximum deviation: O-S-O = 120.23 (14)°]. One of the sulfonamide O atoms is coplanar with the benzene ring [C-C-S-O torsion angle = -174.5 (2)°], whereas the other lies well above the plane [C-C-S-O = 57.0 (3)°]. A chair conformation is found for the cyclo-hexyl ring. In the crystal, supra-molecular chains aligned along the c axis are formed via N-H⋯O hydrogen bonds; these ar  ...[more]

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