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1-[(4-Chloro-phen-yl)(phenyl-imino)-meth-yl]-7-meth-oxy-2-naphthol-1,4-diaza-bicyclo-[2.2.2]octane (2/1).

ABSTRACT: In the crystal structure of the title cocrystal, 2C(24)H(18)ClNO(2)·C(6)H(12)N(2), the 1,4-diaza-bicyclo-[2.2.2]octane mol-ecule is located on a twofold rotation axis and linked to the two triaryl-imine mol-ecules by O-H?N hydrogen bonds, forming a 2:1 aggregate. C-H?Cl inter-actions are also observed. In the triaryl-imine mol-ecule, the naphthalene ring system makes dihedral angles of 80.39?(6) and 82.35?(6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two latter rings is 87.09?(7)°.

SUBMITTER: Nagasawa A

PROVIDER: S-EPMC2983128 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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1-[(4-Chloro-phen-yl)(phenyl-imino)-meth-yl]-7-meth-oxy-2-naphthol-1,4-diaza-bicyclo-[2.2.2]octane (2/1).

Nagasawa Atsushi A Mitsui Ryosuke R Kato Yuichi Y Okamoto Akiko A Yonezawa Noriyuki N

Acta crystallographica. Section E, Structure reports online 20100904 Pt 10

In the crystal structure of the title cocrystal, 2C(24)H(18)ClNO(2)·C(6)H(12)N(2), the 1,4-diaza-bicyclo-[2.2.2]octane mol-ecule is located on a twofold rotation axis and linked to the two triaryl-imine mol-ecules by O-H⋯N hydrogen bonds, forming a 2:1 aggregate. C-H⋯Cl inter-actions are also observed. In the triaryl-imine mol-ecule, the naphthalene ring system makes dihedral angles of 80.39 (6) and 82.35 (6)°, respectively, with the phenyl and benzene rings. The dihedral angle between these two ...[more]

PMID: 21587495

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