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{Bis[2-(3,5-dimethyl-pyrazol-1-yl-?N)eth-yl]amine-?N}chloridopalladium(II) chloride 0.25-hydrate.

ABSTRACT: The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ?). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584?(4):0.416?(4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6?(6)° to each other, to mitigate steric conflict between their methyl groups.

SUBMITTER: Guzei IA

PROVIDER: S-EPMC2983137 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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{Bis[2-(3,5-dimethyl-pyrazol-1-yl-κN)eth-yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate.

Guzei Ilia A IA Spencer Lara C LC Miti Nangamso N Darkwa James J

Acta crystallographica. Section E, Structure reports online 20100911 Pt 10

The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ▶). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict ...[more]

PMID: 21587393

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