Unknown

Dataset Information

0

Bis[2-(4-benzo-yloxy-2-hy-droxy-benzo-yl)-1-phenyl-ethenolato]diethano-lzinc(II).

ABSTRACT: The mononuclear title complex, [Zn(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], contains a Zn(II) atom (site symmetry ) surrounded by six O atoms of the keto groups of two substituted 1,3-diketonate ligands and of two ethanol mol-ecules, resulting in a distorted octa-hedral coordination environment. The mol-ecular configuration is stabilized by an intra-molecular hydrogen bond between the phenolic hy-droxy group and the adjacent keto group. The hy-droxy group acts likewise as an acceptor of an inter-molecular O-H?O hydrogen bond with the hy-droxy group of the ethanol mol-ecule as the donor. The hydrogen-bonding scheme leads to the formation of supra-molecular layers parallel to (010).

SUBMITTER: Dong K 

PROVIDER: S-EPMC2983159 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis[2-(4-benzo-yloxy-2-hy-droxy-benzo-yl)-1-phenyl-ethenolato]diethano-lzinc(II).

Dong Kai K   Sun Juan J   Ruan Ban-Feng BF   Gong Hai-Bin HB  

Acta crystallographica. Section E, Structure reports online 20100925 Pt 10

The mononuclear title complex, [Zn(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], contains a Zn(II) atom (site symmetry ) surrounded by six O atoms of the keto groups of two substituted 1,3-diketonate ligands and of two ethanol mol-ecules, resulting in a distorted octa-hedral coordination environment. The mol-ecular configuration is stabilized by an intra-molecular hydrogen bond between the phenolic hy-droxy group and the adjacent keto group. The hy-droxy group acts likewise as an acceptor of an inter-mole  ...[more]

Similar Datasets

Unknown Bis[4-(2-benzoyl-1-oxidoethen-yl)-3-hy-droxy-phenyl benzoato]diethano-l-cobalt(II).
| S-EPMC3007494 | biostudies-literature
Unknown Bis{N-[2-hy-droxy-1,1-bis-(hy-droxy-methyl)eth-yl]glycinato-?(3) O,N,O'}iron(II).
| S-EPMC4120612 | biostudies-literature
Unknown Bis(2-hy-droxy-phen-yl)methanone.
| S-EPMC3212291 | biostudies-literature
Unknown 1-(2-Hy-droxy-benzo-yl)thio-semicarbazide hemihydrate.
| S-EPMC3011454 | biostudies-literature
Unknown Bis{2-[bis-(2-hy-droxy-eth-yl)amino]-acetato-κO,N,O'}zinc(II).
| S-EPMC3008976 | biostudies-literature
Unknown Bis(2-hy-droxy-eth-yl)ammonium picrate.
| S-EPMC3884432 | biostudies-literature
Unknown 2-(6-Hy-droxy-1-benzo-furan-3-yl)acetamide.
| S-EPMC3914110 | biostudies-literature
Unknown Bis{4-bromo-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}nickel(II) monohydrate.
| S-EPMC3200792 | biostudies-literature
Unknown 1-[3-(Hy-droxy-meth-yl)phen-yl]-3-phenyl-urea.
| S-EPMC3213536 | biostudies-literature
Unknown 1-(3-Benzyl-4,6-dibenz-yloxy-2-hy-droxy-phen-yl)ethanone.
| S-EPMC3470220 | biostudies-literature