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N'-(Butan-2-yl-idene)furan-2-carbohydrazide.

ABSTRACT: The title Schiff base compound, C(9)H(12)N(2)O(2), was obtained from a condensation reaction of butan-2-one and furan-2-carbohydrazide. The furan ring and the hydrazide fragment are roughly planar, the largest deviation from the mean plane being 0.069?(2)Å, but the butanyl-idene group is twisted slightly with respect to this plane by a dihedral angle of 5.2?(3)°. In the crystal, inter-molecular N-H?O hydrogen bonds link pairs of inversion-related mol-ecules, forming dimers of R(2) (2)(8) graph-set motif.

SUBMITTER: Ma BW

PROVIDER: S-EPMC2983189 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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N'-(Butan-2-yl-idene)furan-2-carbohydrazide.

Ma Bu-Wei BW Zhao Zhen-Xin ZX Li He-Ping HP

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10

The title Schiff base compound, C(9)H(12)N(2)O(2), was obtained from a condensation reaction of butan-2-one and furan-2-carbohydrazide. The furan ring and the hydrazide fragment are roughly planar, the largest deviation from the mean plane being 0.069 (2)Å, but the butanyl-idene group is twisted slightly with respect to this plane by a dihedral angle of 5.2 (3)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link pairs of inversion-related mol-ecules, forming dimers of R(2) (2)(8) graph-s ...[more]

PMID: 21587628

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