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Cabraleahy-droxy-lactone from the leaves of Aglaia exima.


ABSTRACT: Cabraleahy-droxy-lactone, C(27)H(44)O(3), isolated from the leaves of Aglaia exima, has three six-membered rings fused together that adopt chair conformations. Its two five-membered rings are enveloped shaped. The hy-droxy group is in an axial position. It is a hydrogen-bond donor to the carbonyl O atom of an adjacent mol-ecule; the O-H?O inter-actions lead to the formation of a helical chain that runs along the b axis. There are two independent mol-ecules in the asymmetric unit.

SUBMITTER: Loong XM 

PROVIDER: S-EPMC2983197 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Cabraleahy-droxy-lactone from the leaves of Aglaia exima.

Loong Xe Min XM   Mohamad Khalit K   Awang Khalijah K   A Hadi A Hamid AH   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100911 Pt 10


Cabraleahy-droxy-lactone, C(27)H(44)O(3), isolated from the leaves of Aglaia exima, has three six-membered rings fused together that adopt chair conformations. Its two five-membered rings are enveloped shaped. The hy-droxy group is in an axial position. It is a hydrogen-bond donor to the carbonyl O atom of an adjacent mol-ecule; the O-H⋯O inter-actions lead to the formation of a helical chain that runs along the b axis. There are two independent mol-ecules in the asymmetric unit. ...[more]

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