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Catena-Poly[[triphenyl-tin(IV)]-?(2)-[3-(cyclo-hexyl-carbamo-yl)propanoato-?O:O]].

ABSTRACT: The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxyl-ate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intra-molecular carboxyl-ate-carbonyl N-H?O hydrogen bond is responsible for the curved conformation within the carboxyl-ate ligand.

SUBMITTER: Shams-Ul-Islam S 

PROVIDER: S-EPMC2983217 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[triphenyl-tin(IV)]-μ(2)-[3-(cyclo-hexyl-carbamo-yl)propanoato-κO:O]].

Shams-Ul-Islam S S   Bhatti Moazzam H MH   Imtiaz-Ud-Din   Ng Seik Weng SW   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20100918 Pt 10

The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxyl-ate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intra-molecular carboxyl-ate-carbonyl N-H⋯O hydrogen bond is responsible for the curved conformation within the carboxyl-ate ligand. ...[more]

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