Unknown

Dataset Information

0

2,2'-(Disulfanedi-yl)dibenzoic acid-2,9-dimethyl-phenanthroline-tetra-hydro-furan (1/2/1).

ABSTRACT: The asymmetric unit of the title co-crystal solvate, C(14)H(10)O(4)S(2)·2C(14)H(12)N(2)·C(4)H(8)O, comprises a 2,2'-(disulfanedi-yl)dibenzoic acid mol-ecule, two mol-ecules of 2,9-dimethyl-phenanthroline and a tetra-hydro-furan (THF) solvent mol-ecule. Each end of the twisted diacid [dihedral angle between the benzene rings = 74.33?(17)°] forms a strong O-H?N hydrogen bond with a 2,9-dimethyl-phenanthroline mol-ecule, forming a trimeric aggregate. The crystal structure comprises layers of acid and THF mol-ecules, and layers of 2,9-dimethyl-phenanthroline mol-ecules that alternate along the a axis, the main connections between them being of the type C-H?O.

SUBMITTER: Arman HD 

PROVIDER: S-EPMC2983249 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

2,2'-(Disulfanedi-yl)dibenzoic acid-2,9-dimethyl-phenanthroline-tetra-hydro-furan (1/2/1).

Arman Hadi D HD   Kaulgud Trupta T   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20100925 Pt 10

The asymmetric unit of the title co-crystal solvate, C(14)H(10)O(4)S(2)·2C(14)H(12)N(2)·C(4)H(8)O, comprises a 2,2'-(disulfanedi-yl)dibenzoic acid mol-ecule, two mol-ecules of 2,9-dimethyl-phenanthroline and a tetra-hydro-furan (THF) solvent mol-ecule. Each end of the twisted diacid [dihedral angle between the benzene rings = 74.33 (17)°] forms a strong O-H⋯N hydrogen bond with a 2,9-dimethyl-phenanthroline mol-ecule, forming a trimeric aggregate. The crystal structure comprises layers of acid a  ...[more]

Similar Datasets

Unknown Dimethyl 3,3'-diphenyl-2,2'-[(S)-thio-phene-2,5-diylbis(carbonyl-aza-nedi-yl)]dipropano-ate tetra-hydro-furan monosolvate.
| S-EPMC2983431 | biostudies-literature
Unknown 2,2'-(Disulfanedi-yl)dibenzoic acid-N,N'-bis-(4-pyridyl-meth-yl)ethane-dithio-amide (1/1).
| S-EPMC2983272 | biostudies-literature
Unknown 2,9-Bis(5-sulfanylidene-4,5-di-hydro-1,3,4-oxa-diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate.
| S-EPMC3998466 | biostudies-literature
Unknown 4,4'-[(2R*,3R*,4R*,5R*)-3,4-Dimethyl-tetra-hydro-furan-2,5-di-yl]diphenol.
| S-EPMC3470375 | biostudies-literature
Unknown Triphen-yl(tetra-hydro-furan)-aluminium(III).
| S-EPMC2959725 | biostudies-literature
Unknown Dichlorido(3,5-dimethyl-1H-pyrazole-κN)[hydro-tris-(3,5-dimethyl-1H-pyrazol-1-yl-κN)borato]chromium(III) tetra-hydro-furan mono-solvate.
| S-EPMC3051926 | biostudies-literature
Unknown 2,2'-(Disulfanedi-yl)dianilinium dichloride dihydrate.
| S-EPMC3770359 | biostudies-literature
Unknown Bis(?-2-{bis-[(2-oxidobenzyl-idene)amino]-meth-yl}phenolato)bis-[(tetra-hydro-furan)-samarium(III)] tetra-hydro-furan disolvate.
| S-EPMC3344343 | biostudies-literature
Unknown Tris(tetra-hydro-furan-?O)tris-[tris-(thio-phen-2-yl)methano-lato-?O]terbium(III) tetra-hydro-furan monosolvate.
| S-EPMC3238632 | biostudies-literature
Unknown Aqua-(2,9-dimethyl-1,10-phenanthroline-?N,N')bis-(2-hydroxy-benzoato-?O)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate.
| S-EPMC2968132 | biostudies-literature