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6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris-(thio-cyanato-?N)cuprate(I).

ABSTRACT: The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter-acting cations and trigonal-planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16?Å. The Cu(I) atom is displaced by 0.019?(2)?Å out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.

SUBMITTER: Xu N

PROVIDER: S-EPMC2983325 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris-(thio-cyanato-κN)cuprate(I).

Xu Na N Niu Yun-Yin YY Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100918 Pt 10

The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter-acting cations and trigonal-planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45. ...[more]

PMID: 21587424

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