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(?-Penta-methyl-cyclo-penta-dien-yl)(?-toluene)-ruthenium(II) hexa-fluorido-phosphate.

ABSTRACT: In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706?(5)?Å and the distance between the Ru atom and the cyclo-penta-dienyl ring is 1.811?(5)?Å. The crystal structure is stabilized by weak C-H?F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies.

SUBMITTER: O WW

PROVIDER: S-EPMC2983397 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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(η-Penta-methyl-cyclo-penta-dien-yl)(η-toluene)-ruthenium(II) hexa-fluorido-phosphate.

O Wylie W N WW Lough Alan J AJ Morris Robert H RH

Acta crystallographica. Section E, Structure reports online 20100915 Pt 10

In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclo-penta-dienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C-H⋯F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies. ...[more]

PMID: 21587411

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