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Bromidotricarbon-yl[4-iodo-N-(pyridin-2-yl-methyl-idene)aniline-?N,N']rhenium(I).

ABSTRACT: In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa-hedron, arising from the N,N'-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-yl-methyl-idene)aniline ligand is 46.2?(3)°. The bromide ion and its corresponding trans CO mol-ecule are disordered over two sets of sites in a 0.966?(3):0.034?(3) ratio.

SUBMITTER: Dehghanpour S 

PROVIDER: S-EPMC2983412 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Bromidotricarbon-yl[4-iodo-N-(pyridin-2-yl-methyl-idene)aniline-κN,N']rhenium(I).

Dehghanpour Saeed S   Mahmoudi Ali A  

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10

In the title compound, [ReBr(C(12)H(9)IN(2))(CO)(3)], the coordination geometry of the Re(I) ion is a distorted fac-ReC(3)BrN(2) octa-hedron, arising from the N,N'-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-yl-methyl-idene)aniline ligand is 46.2 (3)°. The bromide ion and its corresponding trans CO mol-ecule are disordered over two sets of sites in a 0.966 (3):0.034 (3) ratio. ...[more]

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