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Catena-Poly[[silver(I)-?-4-aminopyridine] perchlorate]: a 1-D staircase coordination polymer.


ABSTRACT: Reaction of 4-amino-pyridine with silver(I) perchlorate leads to a one-dimensional coordination polymer, {[Ag(C(5)H(6)N(2))]ClO(4)}(n), in which the amino-pyridine binds through both N atoms. The perchlorate anion is hydrogen bonded to the amino H atoms and inter-acts weakly with the silver(I) atoms (Ag-O > 2.70?Å), both located on inversion centres, and some aromatic H atoms (O-H > 2.55?ÅA), thereby extending the dimensionality of the assembly. This is the first silver complex in which this ligand acts in a bridging mode.

SUBMITTER: Golder RK 

PROVIDER: S-EPMC2983413 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[silver(I)-μ-4-aminopyridine] perchlorate]: a 1-D staircase coordination polymer.

Golder Ryan K RK   Fitchett Christopher M CM   Wikaira Jan L JL   Steel Peter J PJ  

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10


Reaction of 4-amino-pyridine with silver(I) perchlorate leads to a one-dimensional coordination polymer, {[Ag(C(5)H(6)N(2))]ClO(4)}(n), in which the amino-pyridine binds through both N atoms. The perchlorate anion is hydrogen bonded to the amino H atoms and inter-acts weakly with the silver(I) atoms (Ag-O > 2.70 Å), both located on inversion centres, and some aromatic H atoms (O-H > 2.55 ÅA), thereby extending the dimensionality of the assembly. This is the first silver complex in which this lig  ...[more]

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