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Aqua-{N-[(4-methyl-phen-yl)sulfon-yl]glycinato(2-)-?N,O}(1,10-phenan-throline)copper(II).

ABSTRACT: In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl-glycinate ligand, one O atom from the carboxyl-ate part of the N-tosyl-glycinate ligand and a water O atom. Inter-molecular O-H?O hydrogen bonds involving the water H atoms link neighboring mol-ecules into supra-molecular chains along [010]. Weak ?-? stacking inter-actions [centroid-centroid distances of 3.456?(1) and 3.691?(1)?Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent mol-ecules extend the chains into a layer structure parallel to (001).

SUBMITTER: Huang ML 

PROVIDER: S-EPMC2983433 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Aqua-{N-[(4-methyl-phen-yl)sulfon-yl]glycinato(2-)-κN,O}(1,10-phenan-throline)copper(II).

Huang Miao-Ling ML  

Acta crystallographica. Section E, Structure reports online 20100915 Pt 10

In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl-glycinate ligand, one O atom from the carboxyl-ate part of the N-tosyl-glycinate ligand and a water O atom. Inter-molecular O-H⋯O hydrogen bonds involving the water H atoms link neighboring mol-ecules into supra-molecular chains along [010]. Weak π-π  ...[more]

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