Unknown

Dataset Information

0

Aqua-{N-[(4-methyl-phen-yl)sulfon-yl]glycinato(2-)-?N,O}(1,10-phenan-throline)copper(II).

ABSTRACT: In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl-glycinate ligand, one O atom from the carboxyl-ate part of the N-tosyl-glycinate ligand and a water O atom. Inter-molecular O-H?O hydrogen bonds involving the water H atoms link neighboring mol-ecules into supra-molecular chains along [010]. Weak ?-? stacking inter-actions [centroid-centroid distances of 3.456?(1) and 3.691?(1)?Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent mol-ecules extend the chains into a layer structure parallel to (001).

SUBMITTER: Huang ML 

PROVIDER: S-EPMC2983433 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Aqua-{N-[(4-methyl-phen-yl)sulfon-yl]glycinato(2-)-κN,O}(1,10-phenan-throline)copper(II).

Huang Miao-Ling ML  

Acta crystallographica. Section E, Structure reports online 20100915 Pt 10

In the title complex, [Cu(C(9)H(9)NO(4)S)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl-glycinate ligand, one O atom from the carboxyl-ate part of the N-tosyl-glycinate ligand and a water O atom. Inter-molecular O-H⋯O hydrogen bonds involving the water H atoms link neighboring mol-ecules into supra-molecular chains along [010]. Weak π-π  ...[more]

Similar Datasets

Unknown catena-Poly[[[aqua-(1,10-phenan-throline)cadmium(II)]-?-benzene-1,4-dicarboxyl-ato] benzene-1,4-dicarboxylic acid hemisolvate].
| S-EPMC2968137 | biostudies-literature
Unknown Chloridobis(1,10-phenanthroline)zinc(II) tetra-chlorido(1,10-phenan-throline)bis-muthate(III) monohydrate.
| S-EPMC3050139 | biostudies-literature
Unknown (2-Hy-droxy-acetato-?O)bis-(1,10-phenan-throline-?N,N')copper(II) nitrate.
| S-EPMC3089357 | biostudies-other
Unknown N-(2-Formyl-phen-yl)-4-methyl-N-[(4-methyl-phen-yl)sulfon-yl]benzene-sulfon-amide.
| S-EPMC4051026 | biostudies-literature
Unknown 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate.
| S-EPMC3152050 | biostudies-literature
Unknown (Carbonato-?O,O')bis-(1,10-phenan-throline-?N,N')cobalt(III) nitrate monohydrate.
| S-EPMC2980272 | biostudies-literature
Unknown Methyl 4-{[(4-methyl-phen-yl)sulfon-yl]amino}-benzoate.
| S-EPMC3295455 | biostudies-literature
Unknown N-[(4-Methyl-phen-yl)sulfon-yl]acetamide.
| S-EPMC3393294 | biostudies-literature
Unknown [4-(Methyl-sulfon-yl)phen-yl]acetic acid.
| S-EPMC2960061 | biostudies-literature
Unknown 2-[4-(Methyl-sulfon-yl)phen-yl]acetonitrile.
| S-EPMC3052001 | biostudies-literature