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(Acetato-?O)(2,2'-bipyridine-?N,N')trimethyl-platinum(IV) monohydrate.

ABSTRACT: In the title hydrate, [Pt(CH(3))(3)(CH(3)COO)(C(10)H(8)N(2))]·H(2)O, the Pt(IV) atom exhibits a distorted octa-hedral coordination geometry built up by three methyl ligands in a facial arrangement, a bipyridine ligand and a monodentately bound acetate ligand. In the crystal structure, inter-molecular O-H?O hydrogen bonds are observed between the water mol-ecule and the platinum complex, which link the mol-ecules into chains along the c axis.

SUBMITTER: Vetter C

PROVIDER: S-EPMC2983493 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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(Acetato-κO)(2,2'-bipyridine-κN,N')trimethyl-platinum(IV) monohydrate.

Vetter Cornelia C Wagner Christoph C Steinborn Dirk D

Acta crystallographica. Section E, Structure reports online 20100213 Pt 3

In the title hydrate, [Pt(CH(3))(3)(CH(3)COO)(C(10)H(8)N(2))]·H(2)O, the Pt(IV) atom exhibits a distorted octa-hedral coordination geometry built up by three methyl ligands in a facial arrangement, a bipyridine ligand and a monodentately bound acetate ligand. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds are observed between the water mol-ecule and the platinum complex, which link the mol-ecules into chains along the c axis. ...[more]

PMID: 21580231

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