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7-Chloro-4-[(E)-2-(2-methoxy-benzyl-idene)hydrazin-1-yl]quinoline monohydrate.

ABSTRACT: In the title hydrate, C(17)H(14)ClN(3)O·H(2)O, the dihedral angle between the quinoline fused-ring system and the benzene ring is 13.4?(2)° and the conformation about the C=N bond is E. In the crystal, N(h)-H?O(w) and O(w)-H?N(q) (h = hydro-zone, w = water and q = quinoline) hydrogen bonds generate a two-dimenstional network in the ac plane. A weak C-H?O inter-action helps to consolidate the packing.

SUBMITTER: de Souza MV

PROVIDER: S-EPMC2983501 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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7-Chloro-4-[(E)-2-(2-methoxy-benzyl-idene)hydrazin-1-yl]quinoline monohydrate.

de Souza Marcus V N MV Howie R Alan RA Tiekink Edward R T ER Wardell James L JL Wardell Solange M S V SM Kaiser Carlos R CR

Acta crystallographica. Section E, Structure reports online 20100227 Pt 3

In the title hydrate, C(17)H(14)ClN(3)O·H(2)O, the dihedral angle between the quinoline fused-ring system and the benzene ring is 13.4 (2)° and the conformation about the C=N bond is E. In the crystal, N(h)-H⋯O(w) and O(w)-H⋯N(q) (h = hydro-zone, w = water and q = quinoline) hydrogen bonds generate a two-dimenstional network in the ac plane. A weak C-H⋯O inter-action helps to consolidate the packing. ...[more]

PMID: 21580438

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