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2,6-Diethyl-anilinium perchlorate.


ABSTRACT: The asymmetric unit of the title mol-ecular salt, C(10)H(16)N(+)·ClO(4) (-), contains two cations and two anions. The atoms of one of the ethyl side chains of one of the cations are disordered over two sets of sites in a 0.531?(13):0.469?(13) ratio. In the crystal, the components are linked by N-H?O and bifurcated N-H?(O,O) hydrogen bonds and weaker C-H?O inter-actions, such that the organic cations alternate with the perchlorate anions, forming ribbons in the a-axis direction.

SUBMITTER: Smirani Sta W 

PROVIDER: S-EPMC2983530 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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2,6-Diethyl-anilinium perchlorate.

Smirani Sta Wajda W   Rzaigui Mohamed M   S Al-Deyab Salem S  

Acta crystallographica. Section E, Structure reports online 20100213 Pt 3


The asymmetric unit of the title mol-ecular salt, C(10)H(16)N(+)·ClO(4) (-), contains two cations and two anions. The atoms of one of the ethyl side chains of one of the cations are disordered over two sets of sites in a 0.531 (13):0.469 (13) ratio. In the crystal, the components are linked by N-H⋯O and bifurcated N-H⋯(O,O) hydrogen bonds and weaker C-H⋯O inter-actions, such that the organic cations alternate with the perchlorate anions, forming ribbons in the a-axis direction. ...[more]

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