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Catena-Poly[[[aqua-silver(I)]-?-4,4'-bipyridine-?N:N'] 4-amino-benzoate nitrate hydrate].

ABSTRACT: In the structure of the title compound, 2[Ag(C(10)H(8)N(2))(H(2)O)](C(7)H(6)NO(2))(NO(3))·H(2)O, the Ag(I) atom is three-coordinated in a T-shaped configuration by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) ligands at short distances and by one water O atom at a longer distance. Each bipy ligand bridges two neighbouring Ag(I) atoms, forming a chain structure extending parallel to [101]. The complete 4-amino-benzoate anion, the nitrate anion and the uncoordinated water mol-ecule are located on mirror planes: together with the coordinated water mol-ecule, they form N-H?O, O-H?O and O-H?N hydrogen bonds, stabilizing the crystal structure.

SUBMITTER: Zhang YM

PROVIDER: S-EPMC2983544 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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catena-Poly[[[aqua-silver(I)]-μ-4,4'-bipyridine-κN:N'] 4-amino-benzoate nitrate hydrate].

Zhang Yong-Mei YM Hou Dong-Yan DY Xin Guang G Li Tie-Chun TC

Acta crystallographica. Section E, Structure reports online 20100213 Pt 3

In the structure of the title compound, 2[Ag(C(10)H(8)N(2))(H(2)O)](C(7)H(6)NO(2))(NO(3))·H(2)O, the Ag(I) atom is three-coordinated in a T-shaped configuration by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) ligands at short distances and by one water O atom at a longer distance. Each bipy ligand bridges two neighbouring Ag(I) atoms, forming a chain structure extending parallel to [101]. The complete 4-amino-benzoate anion, the nitrate anion and the uncoordinated water mol-ecule ...[more]

PMID: 21580232

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