Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Anilinium hydrogen sulfate.

ABSTRACT: The asymmetric unit of the title compound, C(6)H(8)N(+)·HSO(4) (-), contains two cations and two anions which are linked to each other through N-H?O hydrogen bonds, formed by all H atoms covalently bonded to the N atoms. In addition, strong O-H?O anion-anion hydrogen-bond inter-actions are also observed.

SUBMITTER: Boutobba Z

PROVIDER: S-EPMC2983547 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Anilinium hydrogen sulfate.

Boutobba Zina Z Direm Amani A Benali-Cherif Nourredine N

Acta crystallographica. Section E, Structure reports online 20100213 Pt 3

The asymmetric unit of the title compound, C(6)H(8)N(+)·HSO(4) (-), contains two cations and two anions which are linked to each other through N-H⋯O hydrogen bonds, formed by all H atoms covalently bonded to the N atoms. In addition, strong O-H⋯O anion-anion hydrogen-bond inter-actions are also observed. ...[more]

PMID: 21580357

Similar Datasets

4-Bromo-3-methyl-anilinium hydrogen sulfate.

Project description:In the cation of the title compound, C(7)H(9)BrN(+)·HSO(4) (-), the amino N atom is protonated. In the crystal, inter-molecular O-H?O and N-H?O hydrogen bonds generate an infinite two-dimensional network parallel to (001).

| S-EPMC2970329 | biostudies-literature

Bis(3-nitro-anilinium) sulfate.

Project description:In the title salt, 2C(6)H(7)N(2)O(2) (+)·SO(4) (2-), all the non-H atoms of both cations and the S atom and two O atoms of the anion lie on a crystallographic mirror plane. In the crystal structure, N-H?O and C-H?O hydrogen bonds help to establish the packing.

| S-EPMC2977765 | biostudies-literature

Bis[3-(dihydroxy-boryl)anilinium] sulfate.

Project description:In the title compound, 2C(6)H(9)BNO(2) (+)·SO(4) (2-), the dihydroxy-boryl group of one of the two independent boronic acid mol-ecules participates in (B)O-H?O(B) and N-H?O(B) hydrogen bonds, while the second is involved mainly in the formation of the charge-assisted heterodimeric synthon -B(OH)(2)?(-)O(2)SO(2) (-). These aggregates are further connected through N-H?O(sulfate) inter-actions, forming a complex three-dimensional hydrogen-bonded network.

| S-EPMC2979015 | biostudies-literature

Bis(4-ethoxy-anilinium) sulfate trihydrate.

Project description:The structure of the title compound, 2C(8)H(12)NO(+)·SO(4) (2-)·3H(2)O, consists of organic layers, water mol-ecules and SO(4) (2-) anions which lie within the organic layers. In the crystal, inter-molecular N-H?O, N-H?S O-H?O and O-H?S hydrogen bonds, some of which are bifurcated, stabilize the structure.

| S-EPMC2970180 | biostudies-literature

Bis(2-carboxy-anilinium) sulfate monohydrate.

Project description:In the title hydrated mol-ecular salt, 2C(7)H(8)NO(2) (+)·SO(4) (2-)·H(2)O, each cation in the asymmetric unit is stabilized by an intra-molecular N-H⋯O hydrogen bond. The O atoms of the sulfate ion are disordered over two sets of sites with an occupancy ratio of 0.541 (13):0.459 (13), which possibly optimizes the acceptance of N-H⋯O hydrogen bonds from the cations. The crystal structure also features aromatic π-π stacking [centroid-centroid separation = 3.842 (2) Å] and a C-H⋯π inter-action.

| S-EPMC2983959 | biostudies-literature

4-Bromo-anilinium hydrogen phthalate.

Project description:In the anion of the title compound, C(6)H(7)BrN(+)·C(8)H(5)O(4) (-), the dihedral angles formed by the benzene ring and the mean planes of the -COOH and -COO(-) groups are 20.6?(3) and 83.2?(3)°, respectively. In the crystal, inter-molecular N-H?O and O-H?O hydrogen bonds connect the cations and anions, forming a two-dimensional network parallel to (001).

| S-EPMC3120532 | biostudies-literature

3-Methyl-anilinium hydrogen phthalate.

Project description:The asymmetric unit of the title salt, C(7)H(10)N(+)·C(8)H(5)O(4) (-), consists of two 3-methyl-phenyl-ammonium cations and two hydrogen phthalate anions. There are strong intra-molecular O-H?O hydrogen bonds in the virtually planar (r.m.s. deviations = 0.054?Å) phthalate anions. In the crystal, the cations and anions are connected via an extensive sytem of N-H?O hydrogen bonds into a corrugated layer extended parallel to (001).

| S-EPMC3254560 | biostudies-literature

Bis(4-fluoro-anilinium) sulfate.

Project description:In the crystal of the title molecular salt, 2C(6)H(7)FN(+)·SO(4) (2-), the cations and anions are linked by N-H?O and C-H?O hydrogen bonds into sheets parallel to the ab plane. The crystal studied was found to be a racemic twin with a 0.50?(10):0.50?(10) domain ratio.

| S-EPMC3200818 | biostudies-other

Bis(3-methyl-anilinium) sulfate.

Project description:In the crystal structure of the title salt, 2C(7)H(7)NH(3) (+)·SO(4) (2-), the cations inter-act with the oxyanions through strong charge-assisted N-H?O hydrogen bonds.

| S-EPMC3238843 | biostudies-other

3-Cyano-anilinium hydrogen oxalate hemihydrate.

Project description:In the title hydrated mol-ecular salt, C(7)H(7)N(2) (+)·C(2)HO(4) (-)·0.5H(2)O, contains a 3-cyano-anilinium cation, a hydrogen oxalate anion and half a water mol-ecule in an asymmetric unit. The dihedral angle between the CO(2)(H) and CO(2) planes of the hydrogen oxalate ion is 7.96?(1)°. In the crystal, the components are linked by N-H?O and O-H?O hydrogen bonds, forming a layer lying parallel to the ac plane.

| S-EPMC3379274 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data