Unknown

Dataset Information

0

2-Amino-pyridinium trifluoro-acetate.


ABSTRACT: The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (-), contains four independent 2-amino-pyridinium cations and four independent trifluoro-acetate anions. In the crystal structure, these ions are linked by N-H?O hydrogen bonds, forming four cation-anion pairs each containing an R(2) (2)(8) ring motif. The ion pairs are linked into two independent chains along [100] by N-H?O hydrogen bonds. In addition, C-H?O and C-H?F hydrogen bonds and ??? inter-actions [centoid-centroid separation = 3.6007?(17)?Å] are observed.

SUBMITTER: Hemamalini M 

PROVIDER: S-EPMC2983566 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

altmetric image

Publications

2-Amino-pyridinium trifluoro-acetate.

Hemamalini Madhukar M   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20100227 Pt 3


The asymmetric unit of the title compound, C(5)H(7)N(2) (+)·C(2)F(3)O(2) (-), contains four independent 2-amino-pyridinium cations and four independent trifluoro-acetate anions. In the crystal structure, these ions are linked by N-H⋯O hydrogen bonds, forming four cation-anion pairs each containing an R(2) (2)(8) ring motif. The ion pairs are linked into two independent chains along [100] by N-H⋯O hydrogen bonds. In addition, C-H⋯O and C-H⋯F hydrogen bonds and π⋯π inter-actions [centoid-centroid  ...[more]

Similar Datasets

| S-EPMC2984062 | biostudies-literature
| S-EPMC3588927 | biostudies-literature
| S-EPMC2983956 | biostudies-literature
| S-EPMC2983973 | biostudies-literature
| S-EPMC2983996 | biostudies-literature
| S-EPMC2962139 | biostudies-literature
| S-EPMC2970170 | biostudies-literature
| S-EPMC3684927 | biostudies-literature
| S-EPMC2971316 | biostudies-literature
| S-EPMC2979470 | biostudies-literature