Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxy-benzyl-idene)hydrazin-yl]ethanaminium} tetra-chlorido-zincate(II) methanol solvate.

ABSTRACT: The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra-chlorido-zincate anion and a mol-ecule of methanol as solvate. These components are inter-connected in the crystal structure by an extensive network of O-H?O, N-H?O, C-H?O, O-H?N, O-H?Cl, N-H?Cl and C-H?Cl hydrogen bonds. The shortest inter-molecular inter-action is realized between the cation and anion [H?Cl = 2.29?(5)?Å; O-H?Cl = 167?(3)°]. C-H?O inter-actions also play a important role in the inter-connection of the cations.

SUBMITTER: Novakovic SB 

PROVIDER: S-EPMC2983568 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature