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Catena-Poly[trimethyl-phenyl-ammonium [[bromidocad-mate(II)]-?-bromido-?-chlorido]].

ABSTRACT: In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif.

SUBMITTER: Lo KM

PROVIDER: S-EPMC2983584 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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catena-Poly[trimethyl-phenyl-ammonium [[bromidocad-mate(II)]-μ-bromido-μ-chlorido]].

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100217 Pt 3

In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif. ...[more]

PMID: 21580250

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