Unknown

Dataset Information

0

6-Fluoro-1,3,4-triphenyl-1H-pyrazolo[3,4-b]quinoline benzene hemisolvate.

ABSTRACT: In the title compound, C(28)H(18)FN(3)·0.5C(6)H(6), the 1H-pyrazolo[3,4-b]quinoline core is almost planar (r.m.s = 0.0371?Å, maximum deviation = 0.0571?Å) and aromatic. The solvent benzene mol-ecules are located around inversion centres. In the crystal, mol-ecules related by centres of symmetry form dimers, with distances of 3.932?(3)?Å between best planes through the fused core due to ??? stacking. The phenyl substituents at positions 1, 3 and 4, are twisted away from the core, making dihedral angles of 29.66?(7), 44.59?(7) and 67.94?(6)°, respectively.

SUBMITTER: Szlachcic P 

PROVIDER: S-EPMC2983603 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

6-Fluoro-1,3,4-triphenyl-1H-pyrazolo[3,4-b]quinoline benzene hemisolvate.

Szlachcic Paweł P   Stadnicka Katarzyna K  

Acta crystallographica. Section E, Structure reports online 20100210 Pt 3

In the title compound, C(28)H(18)FN(3)·0.5C(6)H(6), the 1H-pyrazolo[3,4-b]quinoline core is almost planar (r.m.s = 0.0371 Å, maximum deviation = 0.0571 Å) and aromatic. The solvent benzene mol-ecules are located around inversion centres. In the crystal, mol-ecules related by centres of symmetry form dimers, with distances of 3.932 (3) Å between best planes through the fused core due to π⋯π stacking. The phenyl substituents at positions 1, 3 and 4, are twisted away from the core, making dihedral  ...[more]

Similar Datasets

Unknown 3-Methyl-1,4-diphenyl-1H-pyrazolo-[3,4-b]quinoline.
| S-EPMC3009067 | biostudies-literature
Unknown 1,3-Diphenyl-8-trifluoro-methyl-1H-pyrazolo-[3,4-b]quinoline.
| S-EPMC3394066 | biostudies-literature
Unknown 3-Iodo-1H-pyrazolo-[3,4-b]pyridine.
| S-EPMC4051060 | biostudies-literature
Unknown 4-Benzyl-sulfanyl-1H-pyrazolo-[3,4-d]pyrimidine.
| S-EPMC3884315 | biostudies-literature
Unknown 3,4,6-Trimethyl-1-phenyl-1H-pyrazolo-[3,4-b]pyridine.
| S-EPMC3007300 | biostudies-literature
Unknown 2-(4-Fluoro-phen-yl)-1,4,5-triphenyl-1H-imidazole.
| S-EPMC2983138 | biostudies-literature
Unknown trans-Dichloridobis(triphenyl-phosphane-?P)palladium(II) benzene hemisolvate.
| S-EPMC3343891 | biostudies-other
Unknown 3,4-Dinitro-1H-pyrazole benzene 0.25-solvate.
| S-EPMC3120617 | biostudies-literature
Unknown 3-Ethyl-6-[3-(4-fluoro-phen-yl)-1H-pyrazol-4-yl]-1,2,4-triazolo[3,4-b][1,3,4]thia-diazole.
| S-EPMC3009212 | biostudies-literature
Unknown 2-[(1H-Benzimidazol-1-yl)meth-yl]phenol benzene hemisolvate.
| S-EPMC3998331 | biostudies-literature