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Bis(oxonium) tetra-kis(o-toluidinium) cyclo-hexa-phosphate.

ABSTRACT: In the title compound, 4C(7)H(10)N(+)·2H(3)O(+)·P(6)O(18) (6-), the complete cyclo-hexa-phosphate anion is generated by crystallographic inversion symmetry. In the crystal, the H(3)O(+) ions and the [P(6)O(18)](6-) anions are linked by O-H?O hydrogen bonds, generating infinite layers lying parallel to the ab plane at z = 1/2. These layers are inter-connected by the organic cations, which establish N-H?O hydrogen bonds with the [P(6)O(18)](6-) anions.

SUBMITTER: Marouani H

PROVIDER: S-EPMC2983635 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Bis(oxonium) tetra-kis(o-toluidinium) cyclo-hexa-phosphate.

Marouani Houda H Rzaigui Mohamed M Al-Deyab Salem S SS

Acta crystallographica. Section E, Structure reports online 20100227 Pt 3

In the title compound, 4C(7)H(10)N(+)·2H(3)O(+)·P(6)O(18) (6-), the complete cyclo-hexa-phosphate anion is generated by crystallographic inversion symmetry. In the crystal, the H(3)O(+) ions and the [P(6)O(18)](6-) anions are linked by O-H⋯O hydrogen bonds, generating infinite layers lying parallel to the ab plane at z = 1/2. These layers are inter-connected by the organic cations, which establish N-H⋯O hydrogen bonds with the [P(6)O(18)](6-) anions. ...[more]

PMID: 21580440

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