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Penta-aqua-(acetonitrile-?N)zinc(II) 4,6-dihydroxy-benzene-1,3-disulfonate trihydrate.

ABSTRACT: In the title compound, [Zn(CH(3)CN)(H(2)O)(5)](C(6)H(4)O(8)S(2))·3H(2)O, the Zn(II) ion lies on a mirror plane and is octa-hedrally coordinated by one acetonitrile ligand and five water mol-ecules. The 4,6-dihydroxy-benzene-1,3-disulfonate anion, acting as a counter-ion, is also located on the mirror plane. The crystal packing is stabilized by O-H?O hydrogen bonds, forming a three-dimensional supra-molecular network.

SUBMITTER: Xie BY

PROVIDER: S-EPMC2983642 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Penta-aqua-(acetonitrile-κN)zinc(II) 4,6-dihydroxy-benzene-1,3-disulfonate trihydrate.

Xie Bu-Yun BY Huang Wei W Zhang Ying Y Yang Rui-Qing RQ Xie Yong-Rong YR

Acta crystallographica. Section E, Structure reports online 20100227 Pt 3

In the title compound, [Zn(CH(3)CN)(H(2)O)(5)](C(6)H(4)O(8)S(2))·3H(2)O, the Zn(II) ion lies on a mirror plane and is octa-hedrally coordinated by one acetonitrile ligand and five water mol-ecules. The 4,6-dihydroxy-benzene-1,3-disulfonate anion, acting as a counter-ion, is also located on the mirror plane. The crystal packing is stabilized by O-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular network. ...[more]

PMID: 21580273

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