Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Poly[[(?(3)-isonicotinato-?O:O:N)(triphenyl-phosphine-?P)silver(I)] ethanol solvate].

ABSTRACT: In the crystal structure of {[Ag(C(6)H(4)NO(2))(C(18)H(15)P)]·C(2)H(6)O}(n), the 4-pyridylcarboxyl-ate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitro-gen atom of the aromatic ring, giving a distorted tetra-hedral coordination at the metal atom. The ?(3)-bridging mode leads to a layer motif; the disordered ethanol mol-ecules are linked to the free carboxyl oxygen atom by O-H?O hydrogen bonds.

SUBMITTER: Sadeghi O

PROVIDER: S-EPMC2983679 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Poly[[(μ(3)-isonicotinato-κO:O:N)(triphenyl-phosphine-κP)silver(I)] ethanol solvate].

Sadeghi Omid O Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100213 Pt 3

In the crystal structure of {[Ag(C(6)H(4)NO(2))(C(18)H(15)P)]·C(2)H(6)O}(n), the 4-pyridylcarboxyl-ate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitro-gen atom of the aromatic ring, giving a distorted tetra-hedral coordination at the metal atom. The μ(3)-bridging mode leads to a layer motif; the disordered ethanol mol-ecules are linked to the free carboxyl oxygen atom b ...[more]

PMID: 21580230

Similar Datasets

Bis(triphenyl-phosphine-?P)(tropolonato-?O,O')silver(I) dichloro-methane solvate.

Project description:The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.

| S-EPMC2968127 | biostudies-literature

Nitratotris(triphenyl-phosphine)copper(I) methanol solvate.

Project description:The title compound, [Cu(NO(3))(C(18)H(15)P)(3)]·CH(3)OH, is a methanol solvate derivative of nitratotris(triphenyl-phos-phine)copper(I). The complex crystallizes with three triphenyl-phosphine ligands coordinated to the copper centre, with an O-H?O hydrogen bond observed between the nitrate ligand and the methanol solvent mol-ecule. The coordination around the Cu(I) centre is distorted tetrahedral.

| S-EPMC2968546 | biostudies-literature

Iodidotris(triphenyl-phosphine)copper(I) acetonitrile solvate.

Project description:The title compound, [CuI(C(18)H(15)P)(3)]·C(2)H(3)N, was obtained from the reaction of triphenyl-phosphine and copper(I) iodide in acetonitrile. The monomeric form of the complex has slightly distorted coordination of Cu by the I atom and three P atoms. The crystal structure is stabilized by C-H⋯π inter-actions between phenyl H atoms and phenyl rings. In addition, the complex mol-ecules exhibit C-H⋯N hydrogen bonds between phenyl H atoms and acetonitrile N atoms. The crystal used was an inversion twin, with nearly equal component populations of 0.522 (8) and 0.478 (8).

| S-EPMC2960968 | biostudies-literature

Poly[[aqua-[μ(3)-(2,6-H(2))-isonicotinato-κN:O:O'][μ(2)-(2,6-H(2))-isonicotinato-κN:O]manganese(II)] ethanol solvate].

Project description:In the title compound, {[Mn(C(6)H(2)D(2)NO(2))(2)(H(2)O)]·C(2)H(6)O}(n), the Mn(II) metal centre displays a slightly distorted octa-hedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water mol-ecule. There are two types of isonicotinate anions, one acting as a bridging tridentate group and the other in a bridging bidentate fashion, to form a polymeric three-dimensional network. The structure is stabilized by intra- and inter-molecular O-H⋯O and C-H⋯O hydrogen-bond inter-actions.

| S-EPMC2961953 | biostudies-literature

(Benzonitrile-?N)chlorido[hydrido-tris(pyrazol-1-yl-?N)borato](triphenyl-phosphine-?P)ruthenium(II) ethanol solvate.

Project description:The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo-nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa-hedron with an average N-Ru-N bite angle of the Tp ligand of 86.6?(2)°.

| S-EPMC2968787 | biostudies-literature

Poly[?(3)-acetato-di-?(3)-isonicotinato-?(2)-isonicotinato-samarium(III)silver(I)].

Project description:In the title homochiral three-dimensional heterometallic complex, [AgSm(C(6)H(4)NO(2))(3)(C(2)H(3)O(2))](n), the eight-coordinate Sm(III) ion displays a bicapped trigonal-prismatic geometry, being coordinated by two O atoms from one acetate ligand, four O atoms from four bridging isonicotinate ligands and two O atoms from two terminal isonicotinate ligands. The four-coordinate Ag(I) ion adopts a tetra-hedral geometry, being bonded to two N atoms from two bridging isonicotinate ligands and two O atoms from two acetate ligands. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network.

| S-EPMC2972026 | biostudies-literature

(Perchlorato-?O)tris-(triphenyl-phosphine-?P)silver(I).

Project description:In the title complex, [Ag(C(18)H(15)P)(3)(ClO(4))], the silver coord-ination environment is dominated by the distorted P(3)AgO tetra-hedron in which Ag-O = 2.608?(12)?Å and the Ag-P bond lengths are 2.5663?(17), 2.5076(16) and 2.5450?(17)?Å. The perchlorate O-atoms are disordered over two positions in a 0.584?(14):0.416?(14) ratio.

| S-EPMC3007391 | biostudies-literature

Tris(3-amino-phen-yl)phosphine oxide ethanol solvate.

Project description:The title compound crystallized as an ethanol solvate, C(18)H(18)N(3)OP·C(2)H(6)O. It is the reduction product of tris-(3-nitro-phen-yl)phosphine oxide. In the crystal, there are inter-molecular N-H⋯O hydrogen bonds between neighbouring tris-(3-amino-phen-yl)phosphine oxide mol-ecules and O-H⋯O hydrogen bonds involving the ethanol solvent mol-ecule.

| S-EPMC2969104 | biostudies-literature

Poly[(?(3)-4-amino-benzene-sulfonato-?N:O:O)(triphenyl-phosphine-?P)silver(I)].

Project description:In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.

| S-EPMC3006886 | biostudies-other

(5-Ammonio-pent-yl)triphenyl-phospho-nium dibromide ethanol solvate.

Project description:The alkyl-ammonium chain of the dication in the title mitochondrially targeted (5-ammonio-pent-yl)triphenyl--phos-pho-nium dibromide ethanol solvate, C(23)H(28)NP(2+)·2Br(-)·C(2)H(6)O, is almost planar (r.m.s deviation = 0.0716?Å for all non-H atoms) and in the extended form, maximizing the P?N distance [7.716?(2)?Å]. The ions and solvent are linked within the crystal by N-H?Br, N-H?O and O-H?Br hydrogen-bonding inter-actions, forming C(3) (2)(6) chains along the b axis, with secondary C-H?Br and C-H?O inter-actions cross-linking the chains.

| S-EPMC2983624 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data