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(R(P))-Menthyl (1-hydroxy-cyclo-hexyl)phenyl-phosphinate.

ABSTRACT: The title compound, C(22)H(35)O(3)P, features a tetra-hedral P atom bonded to a phenyl ring, a hydroxy-cyclo-hexyl unit and the O atom of a menthyl group. The axial chirality at phospho-rus is R(P). In the crystal, mol-ecules are connected through O-H?O hydrogen bonds involving the hydr-oxy and P=O groups, forming chains along the 2(1) screw axis. The methyl groups of the isopropyl fragment in the menthyl unit are disordered over two sites of equal occupancy.

SUBMITTER: Fu B

PROVIDER: S-EPMC2983758 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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(R(P))-Menthyl (1-hydroxy-cyclo-hexyl)phenyl-phosphinate.

Fu Baoci B Zhao Chang-Qiu CQ

Acta crystallographica. Section E, Structure reports online 20100317 Pt 4

The title compound, C(22)H(35)O(3)P, features a tetra-hedral P atom bonded to a phenyl ring, a hydroxy-cyclo-hexyl unit and the O atom of a menthyl group. The axial chirality at phospho-rus is R(P). In the crystal, mol-ecules are connected through O-H⋯O hydrogen bonds involving the hydr-oxy and P=O groups, forming chains along the 2(1) screw axis. The methyl groups of the isopropyl fragment in the menthyl unit are disordered over two sites of equal occupancy. ...[more]

PMID: 21580682

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