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ABSTRACT:
SUBMITTER: Soleimannejad J
PROVIDER: S-EPMC2983936 | biostudies-literature | 2010 Mar
REPOSITORIES: biostudies-literature
Soleimannejad Janet J Aghabozorg Hossein H Sheshmani Shabnam S
Acta crystallographica. Section E, Structure reports online 20100317 Pt 4
In the title compound, (C(10)H(9)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O or (bpyH)[Fe(pydc)(2)]·4H(2)O, the asymmetric unit contains an [Fe(pydc)(2)](-) (pydcH(2)= pyridine-2,6-dicarboxylic acid) anion, a protonated 4,4'-bipyridine as a counter-ion, (bpyH)(+), and four uncoordinated water mol-ecules. The anion is a six-coordinate complex with a distorted octa-hedral geometry around the Fe(III )atom. A wide range of non-covalent inter-actions, i.e. O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds, ion pairing, C ...[more]