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(E)-5-Benzyl-1-methyl-N-nitro-1,3,5-triazinan-2-imine.

ABSTRACT: In the title compound, C(11)H(15)N(5)O(2), the 1,3,5-triazine ring exhibits a half-chair conformation. An intra-molecular N-H⋯O inter-action occurs. In the crystal structure, mol-ecules are connected by inter-molecular C-H⋯O and N-H⋯N hydrogen bonds, forming a zigzag chain along the b axis.

SUBMITTER: Xu LZ

PROVIDER: S-EPMC2983939 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(E)-3-[1-(2,4-Difluoro-phen-yl)eth-yl]-5-methyl-N-nitro-1,3,5-oxadiazinan-4-imine.

Project description:The 1,3,5-oxadiazinane ring in the title compound, C(12)H(14)F(2)N(4)O(3), has a conformation inter-mediate between half-chair and screw-boat. The crystal structure is stabilized by weak inter-molecular C-H?O hydrogen bonds. Weak ?-? inter-actions are indicated by the relatively long centroid-centroid distance of 3.9199?(12)?Å and inter-planar distance of 3.803?Å between symmetry-related benzene rings from neighbouring mol-ecules.

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Project description:In the title compound, C(12)H(15)ClN(4)O(3), which has potential insecticidal activity, the oxadiazine ring and the benzene ring make a dihedral angle of 84.63 (2)° to one another. The crystal packing involves weak inter-molecular C-H⋯O hydrogen bonds.

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Project description:The title compound, C(9)H(8)N(2)O, was prepared from o-xylene by nitration, oxidation, hydrolysis, reduction, chlorination and cyanation. There are two mol-ecules in the asymmetric unit with a dihedral angle of 20.15 (7)° between their aromatic rings.

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Project description:In the title compound, C(13)H(18)ClN(5)O(2), the 1,3,5-triazinane ring exhibits an envelope conformation with an E form. The chloro-phenyl ring and the nitro group are each twisted with respect to the mean plane of the triazinane ring, making dihedral angles of 67.30?(9) and 83.54?(8)°, respectively. In the crystal, weak inter-molecular C-H?O hydrogen bonds build up a corrugated layer parallel to the (101) plane.

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(E)-4-Methyl-N'-(3-nitro-benzyl-idene)benzohydrazide.

Project description:In the title compound, C(15)H(13)N(3)O(3), the dihedral angle between the benzene rings is 1.01?(3)° and that between the nitro group and its attached ring is 5.99?(15)°. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds generating C(4) chains along [010].

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Project description:In the title compound, C(19)H(22)N(4)O(2), the tetra-hydro-pyrimidine ring adopts an envelope conformation (with the N atom connected to the benzyl group representing the flap). This benzyl group occupies a quasi-axial position. The two benzyl groups lie over the tetra-hydro-pyridimidine ring. The amino group is a hydrogen-bond donor to the nitro group.

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N'-[(Z)-4-Methyl-benzyl-idene]-4-nitro-benzohydrazide monohydrate.

Project description:In the title compound, C(15)H(13)N(3)O(3)·H(2)O, the two benzene rings form a dihedral angle of 2.03 (2)°. In the crystal structure, adjacent hydrazide mol-ecules are linked into dimers by water mol-ecules; these dimers are then stacked along the b axis. Inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds and a π-π stacking inter-action between the nitro-benzene and tolyl rings with a centroid-centroid distance of 3.8208 (3) Å are observed. There is also a short O⋯N contact [2.6824 (7) Å].

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