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Bis[?-4-hydr-oxy-N'-(4-meth-oxy-2-oxido-benzyl-idene)benzohydrazidato]bis-[pyridine-copper(II)].

ABSTRACT: In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol-ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107?Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O inter-actions and also O-H?N hydrogen bonds.

SUBMITTER: Mohd Lair N

PROVIDER: S-EPMC2984003 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Bis[μ-4-hydr-oxy-N'-(4-meth-oxy-2-oxido-benzyl-idene)benzohydrazidato]bis-[pyridine-copper(II)].

Mohd Lair Nooraziah N Khaledi Hamid H Mohd Ali Hapipah H Puteh Rustam R

Acta crystallographica. Section E, Structure reports online 20100331 Pt 4

In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol-ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O inter-actions and also O-H⋯N hydrogen b ...[more]

PMID: 21580553

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