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Bis(acetonitrile-?N)(1,10-phenanthroline-?N,N')platinum(II) bis-(perchlorate).

ABSTRACT: The asymmetric unit of the title compound, [Pt(CH(3)CN)(2)(C(12)H(8)N(2))](ClO(4))(2), contains one half of a cationic Pt(II) complex and pair of half perchlorate anions, one of which is disordered over two sites in a 0.53?(3):0.47?(3) ratio. The complex and anions are disposed about a crystallographic mirror plane parallel to the ac plane passing through the Pt and Cl atoms. In the complex, the Pt(II) ion lies in a distorted square-planar environment defined by four N atoms of the chelating 1,10-phenanthroline ligand and two distinct acetonitrile mol-ecules. The component ions inter-act by means of inter-molecular C-H?O hydrogen bonds.

SUBMITTER: Ha K

PROVIDER: S-EPMC2984004 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Bis(acetonitrile-κN)(1,10-phenanthroline-κN,N')platinum(II) bis-(perchlorate).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20100310 Pt 4

The asymmetric unit of the title compound, [Pt(CH(3)CN)(2)(C(12)H(8)N(2))](ClO(4))(2), contains one half of a cationic Pt(II) complex and pair of half perchlorate anions, one of which is disordered over two sites in a 0.53 (3):0.47 (3) ratio. The complex and anions are disposed about a crystallographic mirror plane parallel to the ac plane passing through the Pt and Cl atoms. In the complex, the Pt(II) ion lies in a distorted square-planar environment defined by four N atoms of the chelating 1,1 ...[more]

PMID: 21580495

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