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Potassium (1-methoxy-carbonyl-2-methyl-prop-2-en-2-yl-idene)azinate.

ABSTRACT: In the title compound, K(+)·C(6)H(8)NO(4) (-), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl-ene groups of the anions are always directed towards the coordinated potassium cations. The N-C-C-C torsion angle is 101.2?(2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound.

SUBMITTER: Reuter C

PROVIDER: S-EPMC2984059 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Potassium (1-methoxy-carbonyl-2-methyl-prop-2-en-2-yl-idene)azinate.

Reuter Cédric C Neudörfl Jörg M JM Schmalz Hans-Günther HG

Acta crystallographica. Section E, Structure reports online 20100327 Pt 4

In the title compound, K(+)·C(6)H(8)NO(4) (-), the K(+) cations have a coordination number of seven and are surrounded by four bidentate azinate anions. The methyl-ene groups of the anions are always directed towards the coordinated potassium cations. The N-C-C-C torsion angle is 101.2 (2)°. The orthogonal non-conjugated nature of the salt confirms the supposed geometry and reactivity of this compound. ...[more]

PMID: 21580546

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