Diffusion-limited kinetics of the solution-solid phase transition of molecular substances.
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ABSTRACT:
SUBMITTER: Petsev DN
PROVIDER: S-EPMC298680 | biostudies-literature | 2003 Feb
REPOSITORIES: biostudies-literature
Publications
Diffusion-limited kinetics of the solution-solid phase transition of molecular substances.
Petsev Dimiter N DN Chen Kai K Gliko Olga O Vekilov Peter G PG
Proceedings of the National Academy of Sciences of the United States of America 20030124 3
For critical tests of whether diffusion-limited kinetics is an option for the solution-solid phase transition of molecular substances or whether they are determined exclusively by a transition state, we performed crystallization experiments with ferritin and apoferritin, a unique pair of proteins with identical shells but different molecular masses. We find that the kinetic coefficient for crystallization is identical (accuracy <or=7%) for the pair, indicating diffusion-limited kinetics of cryst ...[more]
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