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Halide exchanged Hoveyda-type complexes in olefin metathesis.


ABSTRACT: The aims of this contribution are to present a straightforward synthesis of 2(nd) generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions.

SUBMITTER: Wappel J 

PROVIDER: S-EPMC3002021 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Halide exchanged Hoveyda-type complexes in olefin metathesis.

Wappel Julia J   Urbina-Blanco César A CA   Abbas Mudassar M   Albering Jörg H JH   Saf Robert R   Nolan Steven P SP   Slugovc Christian C  

Beilstein journal of organic chemistry 20101123


The aims of this contribution are to present a straightforward synthesis of 2(nd) generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions. ...[more]

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