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Trichloridobis(ethyl-diphenyl-phosphine)(tetra-hydro-furan)-molybdenum(III).

ABSTRACT: In the mononuclear title compound, [MoCl(3)(C(4)H(8)O)(C(14)H(15)P)(2)], obtained by the reaction of trichloro-tris-(tetra-hydro-furan)-molybdenum(III) and ethyl-diphenyl-phosphine in tetra-hydro-furan (THF) solution, the Mo(III) atom is six-coordinated by one O atom of a THF mol-ecule, two P atoms from two ethyl-diphenyl-phosphine ligands and three Cl atoms in a distorted octa-hedral geometry. The C atoms of the THF molecule are disordered over two positions in a 0.55?(2):0.45?(2) ratio.

SUBMITTER: Kruczynski T

PROVIDER: S-EPMC3006780 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Trichloridobis(ethyl-diphenyl-phosphine)(tetra-hydro-furan)-molybdenum(III).

Kruczyński Tomasz T Pikies Jerzy J Ponikiewski Lukasz L

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

In the mononuclear title compound, [MoCl(3)(C(4)H(8)O)(C(14)H(15)P)(2)], obtained by the reaction of trichloro-tris-(tetra-hydro-furan)-molybdenum(III) and ethyl-diphenyl-phosphine in tetra-hydro-furan (THF) solution, the Mo(III) atom is six-coordinated by one O atom of a THF mol-ecule, two P atoms from two ethyl-diphenyl-phosphine ligands and three Cl atoms in a distorted octa-hedral geometry. The C atoms of the THF molecule are disordered over two positions in a 0.55 (2):0.45 (2) ratio. ...[more]

PMID: 21587711

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