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Dimethyl 2,2'-[ethane-1,2-diylbis(sulfanedi-yl)]dibenzoate.

ABSTRACT: The title compound, C(18)H(18)O(4)S(2), was synthesized by the reaction of 1,2-dibromo-ethane with methyl thio-salicylate. The complete molecule is generated by crystallographic twofold symmetry: two methyl benzoate units are linked by an -S-(CH(2))(2)-S- bridging chain with a gauche S-CH(2)-CH(2)-S torsion angle [72.88?(16)°]. The two aromatic rings form a dihedral angle of 79.99?(6)°. In the crystal, adjacent mol-ecules are linked into a three-dimensional network by non-classical C-H?O hydrogen bonds.

SUBMITTER: Hu X

PROVIDER: S-EPMC3006883 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Dimethyl 2,2'-[ethane-1,2-diylbis(sulfanedi-yl)]dibenzoate.

Hu Xiaoming X Yu Jianghua J Yuan Limin L

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

The title compound, C(18)H(18)O(4)S(2), was synthesized by the reaction of 1,2-dibromo-ethane with methyl thio-salicylate. The complete molecule is generated by crystallographic twofold symmetry: two methyl benzoate units are linked by an -S-(CH(2))(2)-S- bridging chain with a gauche S-CH(2)-CH(2)-S torsion angle [72.88 (16)°]. The two aromatic rings form a dihedral angle of 79.99 (6)°. In the crystal, adjacent mol-ecules are linked into a three-dimensional network by non-classical C-H⋯O hydroge ...[more]

PMID: 21587900

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