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Dibut-yl{N'-[1-(5-chloro-2-oxidophenyl-κO)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazidato-κN',O}tin(IV).

ABSTRACT: The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bonding, which stabilizes the overall compound.

SUBMITTER: Lee SM

PROVIDER: S-EPMC3006936 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Dibut-yl{N'-[1-(5-chloro-2-oxidophenyl-κO)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazidato-κN',O}tin(IV).

Lee See Mun SM Mohd Ali Hapipah H Lo Kong Mun KM

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bonding, which stabilizes the overall compound. ...[more]

PMID: 21587723

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