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3-Chloro-benzohydrazide.


ABSTRACT: In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30?(11)° with respect to the benzene ring. The amino H atoms form inter-molecular N-H?O hydrogen bonds with the O atoms of two adjacent mol-ecules, resulting in 10-membered rings of graph-set motif R(2) (2)(10). The imino H atom is also involved in an inter-molecular hydrogen bond with an amino N atom of a symmetry-related mol-ecule, resulting in a zigzag chain along the b axis. The structure is further consolidated by an intra-molecular N-H?O inter-action, which results in a five-membered ring.

SUBMITTER: Ashiq U 

PROVIDER: S-EPMC3007237 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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3-Chloro-benzohydrazide.

Ashiq Uzma U   Jamal Rifat Ara RA   Arshad Muhammad Nadeem MN   Khan Islam Ullah IU  

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8


In the title compound, C(7)H(7)ClN(2)O, the hydrazide group is inclined at a dihedral angle of 32.30 (11)° with respect to the benzene ring. The amino H atoms form inter-molecular N-H⋯O hydrogen bonds with the O atoms of two adjacent mol-ecules, resulting in 10-membered rings of graph-set motif R(2) (2)(10). The imino H atom is also involved in an inter-molecular hydrogen bond with an amino N atom of a symmetry-related mol-ecule, resulting in a zigzag chain along the b axis. The structure is fur  ...[more]

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