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2-(4-Methyl-cyclo-hex-3-en-yl)propan-2-yl N-phenyl-carbamate.

ABSTRACT: In the title carbamate compound, C(17)H(23)NO(2), one of the Csp(3) atoms of the cyclo-hexene ring is disordered over two sites with refined occupancies of 0.55?(2) and 0.45?(2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at inter-planar angles of 14.80?(13), 18.30?(17) and 24.0?(2)°, respectively, with respect to the phenyl ring, and the major and minor disorder component cyclo-hexene rings. In the crystal structure, adjacent mol-ecules are linked into chains along [001] via inter-molecular N-H?O hydrogen bonds. The crystal structure is further stabilized by weak inter-molecular C-H?? inter-actions.

SUBMITTER: Ghalib RM 

PROVIDER: S-EPMC3007260 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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2-(4-Methyl-cyclo-hex-3-en-yl)propan-2-yl N-phenyl-carbamate.

Ghalib Raza Murad RM   Sulaiman Othman O   Mehdi Sayed Hasan SH   Goh Jia Hao JH   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20100703 Pt 8

In the title carbamate compound, C(17)H(23)NO(2), one of the Csp(3) atoms of the cyclo-hexene ring is disordered over two sites with refined occupancies of 0.55 (2) and 0.45 (2), both disorder components resulting in half-boat conformations. The mean plane through the carbamate unit is inclined at inter-planar angles of 14.80 (13), 18.30 (17) and 24.0 (2)°, respectively, with respect to the phenyl ring, and the major and minor disorder component cyclo-hexene rings. In the crystal structure, adja  ...[more]

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