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[?-1,2-Bis(diphenyl-phosphino)ethane-?P:P']bis-{[1,2-bis-(diphenyl-phosphino)ethane-?P,P']cyanidocopper(I)} methanol disolvate.

ABSTRACT: The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis-(diphenyl-phosphino)ethane] bridged by one ?(2)-dppe ligand, and two methanol solvent mol-ecules. The angles around the central metal atom indicate that each Cu(I) atom is located in the center of a distorted tetra-hedron. The coordination sphere of each Cu(I) atom is formed by three P atoms from two dppe ligands, and one C atom from the cyanide ligand. The crystal structure is stabilized by O-H?N hydrogen bonds, which are formed by the O-H donor group from methanol and the N-atom acceptor from a cyanide ligand.

SUBMITTER: Wang R 

PROVIDER: S-EPMC3007356 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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[μ-1,2-Bis(diphenyl-phosphino)ethane-κP:P']bis-{[1,2-bis-(diphenyl-phosphino)ethane-κP,P']cyanidocopper(I)} methanol disolvate.

Wang Rong R   Xiao Ye-Lan YL   Jin Qiong-Hua QH   Zhang Cun-Lin CL  

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8

The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis-(diphenyl-phosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent mol-ecules. The angles around the central metal atom indicate that each Cu(I) atom is located in the center of a distorted tetra-hedron. The coordination sphere of each Cu(I) atom is formed by three P atoms from two dppe ligands, and one C atom from the cyanide ligand.  ...[more]

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