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[rac-2-(1-Amino-eth-yl)phenyl-?C,N](ethyl-endiamine-?N,N')palladium(II) 3,5-dimethyl-benzoate.

ABSTRACT: In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(9)H(9)O(2)), the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl-enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex and the 3,5-dimethyl-benzoate anion are inter-connected by N-H?O hydrogen bonds.

SUBMITTER: Serb MD

PROVIDER: S-EPMC3007359 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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[rac-2-(1-Amino-eth-yl)phenyl-κC,N](ethyl-endiamine-κN,N')palladium(II) 3,5-dimethyl-benzoate.

Serb Mihaela-Diana MD Kalf Irmgard I Englert Ulli U

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8

In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(9)H(9)O(2)), the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl-enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex and the 3,5-dimethyl-benzoate anion are inter-connected by N-H⋯O hydrogen bonds. ...[more]

PMID: 21588201

Similar Datasets

[rac-2-(1-Amino-eth-yl)phenyl-?C,N](ethyl-endiamine-?N,N')palladium(II) 3-methyl-benzoate monohydrate.

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rac-4-Chloro-2-[({2-[(3-chloro-6-hy-droxy-2,4-dimethyl-benz-yl)(meth-yl)amino]-prop-yl}(meth-yl)amino)-meth-yl]-3,5-dimethyl-phenol.

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Ethyl 2-[3-(3,5-Dinitrobenzo-yl)thio-ureido]benzoate.

Project description:In the title compound, C(17)H(14)N(4)O(7)S, the dihedral angle between the two benzene rings is 9.04?(15)°. The centroid-centroid distance of 3.9825?(19)?Å between nearly parallel benzene rings of adjacent mol-ecules suggests the existence of ?-? stacking. Inter-molecular and intra-mol-ecular N-H?O hydrogen bonding is present in the structure. The eth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.580?(15):0.420?(15). The crystal studied was an inversion twin.

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(μ-4-Bromo-2-{1-[2-(dimethyl-amino)ethyl-imino]eth-yl}phenolato)bis-[ethyl-zinc(II)].

Project description:The title complex, [Zn(2)(C(2)H(5))(2)(C(12)H(16)BrN(2)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The molecule lies on a crystallographic twofold rotation axis. Each Zn atom is penta-coordinated by two N atoms and two bridging O atoms of the tridentate salicylideneiminate ligands and one C atom from an ethyl group, forming a distorted square-pyramidal environment.

| S-EPMC2915078 | biostudies-literature

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