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Tris(2-meth-oxy-ethanaminium) dodeca-molybdophosphate trihydrate.

ABSTRACT: The asymmetric unit of the polyoxidometalate-based organic-inorganic hybrid title compound, (C(3)H(10)NO)(3)[PMo(12)O(40)]·3H(2)O, consists of one ?-Keggin-type [PMo(12)O(40)](3-) polyoxido-anion, three independent [CH(3)-O-CH(2)-CH(2)-NH(3)](+) cations and three solvent water mol-ecules. The polyoxidoanion shows characteristic features with respect to bond lengths and angles. In the crystal structure, extensive inter-molecular N-H?O and O-H?O hydrogen bonding between the organic cations, inorganic anions and solvent water mol-ecules leads to a three-dimensional supra-molecular network.

SUBMITTER: Raissi Shabari A

PROVIDER: S-EPMC3007375 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Tris(2-meth-oxy-ethanaminium) dodeca-molybdophosphate trihydrate.

Raissi Shabari Akbar A Kharaghani Sara S Pourayoubi Mehrdad M

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

The asymmetric unit of the polyoxidometalate-based organic-inorganic hybrid title compound, (C(3)H(10)NO)(3)[PMo(12)O(40)]·3H(2)O, consists of one α-Keggin-type [PMo(12)O(40)](3-) polyoxido-anion, three independent [CH(3)-O-CH(2)-CH(2)-NH(3)](+) cations and three solvent water mol-ecules. The polyoxidoanion shows characteristic features with respect to bond lengths and angles. In the crystal structure, extensive inter-molecular N-H⋯O and O-H⋯O hydrogen bonding between the organic cations, inorga ...[more]

PMID: 21588083

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