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Tris(2-amino-1,3-thia-zole-?N)(7-oxa-bicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-?O,O,O)cadmium(II) dihydrate.

ABSTRACT: In the crystal structure of the title complex, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2)S)(3)]·2H(2)O, the Cd(II) atom exhibits a slightly distorted octa-hedral CdO(3)N(3) coordination, defined by the bridging O atom of the bicyclo-heptane unit, two O atoms from the carboxyl-ate groups and by three N atoms from three 2-amino-thia-zole ligands. Uncoordinated lattice water mol-ecules are also present in the crystal structure. N-H?O and O-H?O hydrogen-bonding inter-actions link the components into a three-dimensional structure.

SUBMITTER: Wang N

PROVIDER: S-EPMC3007392 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Tris(2-amino-1,3-thia-zole-κN)(7-oxa-bicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κO,O,O)cadmium(II) dihydrate.

Wang Na N Wu Yi-Zhou YZ Lin Qiu-Yue QY

Acta crystallographica. Section E, Structure reports online 20100717 Pt 8

In the crystal structure of the title complex, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2)S)(3)]·2H(2)O, the Cd(II) atom exhibits a slightly distorted octa-hedral CdO(3)N(3) coordination, defined by the bridging O atom of the bicyclo-heptane unit, two O atoms from the carboxyl-ate groups and by three N atoms from three 2-amino-thia-zole ligands. Uncoordinated lattice water mol-ecules are also present in the crystal structure. N-H⋯O and O-H⋯O hydrogen-bonding inter-actions link the components into a three-dim ...[more]

PMID: 21588187

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