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Methyl 4-(4-chloro-phen-yl)-3,3a,4,4a,5,12c-hexa-hydro-2-thia-naphtho-[1',2':3,2]furo[5,4-b]pyrrolizine-4a-carboxyl-ate.

ABSTRACT: In the title compound, C(25)H(22)ClNO(3)S, both the pyrrolidinyl and thia-zolyl rings adopt envelope conformations whereas the dihydro-pyran ring adopts a half-chair conformation. The chloro-phenyl and naphthalenyl ring systems are oriented at a dihedral angle of 59.7?(1)°. The crystal packing is stabilized by an intra-molecular C-H?N hydrogen bond and weak inter-molecular C-H?? inter-actions.

SUBMITTER: Selvanayagam S

PROVIDER: S-EPMC3007469 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Methyl 4-(4-chloro-phen-yl)-3,3a,4,4a,5,12c-hexa-hydro-2-thia-naphtho-[1',2':3,2]furo[5,4-b]pyrrolizine-4a-carboxyl-ate.

Selvanayagam S S Sridhar B B Ravikumar K K Kathiravan S S Raghunathan R R

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the title compound, C(25)H(22)ClNO(3)S, both the pyrrolidinyl and thia-zolyl rings adopt envelope conformations whereas the dihydro-pyran ring adopts a half-chair conformation. The chloro-phenyl and naphthalenyl ring systems are oriented at a dihedral angle of 59.7 (1)°. The crystal packing is stabilized by an intra-molecular C-H⋯N hydrogen bond and weak inter-molecular C-H⋯π inter-actions. ...[more]

PMID: 21588391

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