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Aqua(dimethylformamide){tris[(1-methyl-1H-benzimidazol-2-yl)methyl]amine}nickel(II) dipicrate.

ABSTRACT: In the title complex, [Ni(C(27)H(27)N(7))(C(3)H(7)NO)(H(2)O)](C(6)H(2)N(3)O(7))(2), the Ni(II) ion is coordinated in a slightly distorted octa-hedral coordination evironment by an NiN(4)O(2) ligand set. The tris-(N-methyl-benzimidazol-2-ylmeth-yl)amine ligand is in a tetra-dentate mode while a coordinated water molecule and a dimethyl-formamide ligand complete the coordination. In the crystal structure, inter-molecular O-H?O hydrogen bonds link the cation and one of the pictrate anions into four-component centrosymmetric clusters.

SUBMITTER: Li K

PROVIDER: S-EPMC3007476 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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Aqua(dimethylformamide){tris[(1-methyl-1H-benzimidazol-2-yl)methyl]amine}nickel(II) dipicrate.

Li Ke K Sun Tao T Yang Yang Y Jia Beibei B Wu Huilu H

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8

In the title complex, [Ni(C(27)H(27)N(7))(C(3)H(7)NO)(H(2)O)](C(6)H(2)N(3)O(7))(2), the Ni(II) ion is coordinated in a slightly distorted octa-hedral coordination evironment by an NiN(4)O(2) ligand set. The tris-(N-methyl-benzimidazol-2-ylmeth-yl)amine ligand is in a tetra-dentate mode while a coordinated water molecule and a dimethyl-formamide ligand complete the coordination. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the cation and one of the pictrate anions into four ...[more]

PMID: 21588100

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