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Catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]-?-2-[(piperidin-1-yl)carbothio-ylsulfan-yl]acetato-?O:O'].

ABSTRACT: Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl-ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113?(2)?Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631?(4) for the major occupied site.

SUBMITTER: Keng CT

PROVIDER: S-EPMC3007486 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio-ylsulfan-yl]acetato-κO:O'].

Keng Chun Thy CT Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8

Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl-ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113 (2) Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site. ...[more]

PMID: 21588202

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catena-Poly[[[(acetato-?O,O')cadmium]-?-acetato-?O,O':O'-?-{1,2-bis-[4-(pyridin-3-yl)pyrimidin-2-ylsulfan-yl]ethane}-?N,N] trihydrate].

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