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Catena-Poly[[(1,10-phenanthroline)lead(II)]bis-(?-5-chloro-2-hy-droxy-benzoato)].


ABSTRACT: In the title polymer, [Pb(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))](n), the Pb(II) ion displays a distorted pseudo-octa-hedral coordination geometry. The metal center is coordinated by six O atoms from four 5-chloro-salicylate ligands and two N atoms from a chelating phenanthroline ligand. The polymeric structure is built up from bridging carboxyl-ate O atoms, forming chains along [100]. The crystal structure is stabilized by ?-? inter-actions between the 1,10-phenanthroline and 5-chloro-salicylate ligands, the shortest centroid-centroid separation between neighbouring aromatic rings being 3.652?(1)?Å.

SUBMITTER: Yang L 

PROVIDER: S-EPMC3007493 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[(1,10-phenanthroline)lead(II)]bis-(μ-5-chloro-2-hy-droxy-benzoato)].

Yang Lei L   Li Bing B   Xue Qing Q   Huo Yu Y   Wang Gaopeng G  

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8


In the title polymer, [Pb(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))](n), the Pb(II) ion displays a distorted pseudo-octa-hedral coordination geometry. The metal center is coordinated by six O atoms from four 5-chloro-salicylate ligands and two N atoms from a chelating phenanthroline ligand. The polymeric structure is built up from bridging carboxyl-ate O atoms, forming chains along [100]. The crystal structure is stabilized by π-π inter-actions between the 1,10-phenanthroline and 5-chloro-salicylate lig  ...[more]

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