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Bis[N,N-bis-(diphenyl-phosphan-yl)pentyl-amine-?P,P']platinum(II) bis-(hexa-fluoridophosphate) dichloro-methane disolvate.

ABSTRACT: The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis-(di-phenyl-phosphan-yl)pentyl-amine ligands with an average Pt-P distance of 2.300?(1)?Å. The coordination around the Pt(II) atom shows a highly distorted square-planar geometry, as evidenced by the P-Pt-P bite angles of 70.45?(3) and 70.64?(3)°. The asymmetric unit contains two hexa-fluoridophosphate ions, the metal complex and two dichloro-methane solvent mol-ecules. One of the chloride atoms of one of the dichloro-methane mol-ecules is disordered over two sites in a 0.515?(3):0.485?(3) ratio. C-H?F hydrogen bonds stabilize the crystal packing.

SUBMITTER: Engelbrecht I

PROVIDER: S-EPMC3007544 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Bis[N,N-bis-(diphenyl-phosphan-yl)pentyl-amine-κP,P']platinum(II) bis-(hexa-fluoridophosphate) dichloro-methane disolvate.

Engelbrecht Ilana I Visser Hendrik G HG Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8

The Pt(II) atom in the title compound, [Pt(C(29)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), is coordinated by four P atoms from two bis-(di-phenyl-phosphan-yl)pentyl-amine ligands with an average Pt-P distance of 2.300 (1) Å. The coordination around the Pt(II) atom shows a highly distorted square-planar geometry, as evidenced by the P-Pt-P bite angles of 70.45 (3) and 70.64 (3)°. The asymmetric unit contains two hexa-fluoridophosphate ions, the metal complex and two dichloro-methane solvent mol-ecule ...[more]

PMID: 21588157

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