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5-Bromo-1H-thieno[2,3-d]imidazole.

ABSTRACT: The crystal structure of the title compound, C(5)H(3)BrN(2)S, shows that bromination of 1H-thieno[2,3-d]imidazole with N-bromo-succinimide in acetonitrile occurs at position 5 of the bicyclic system. The mol-ecule is almost planar, with a mean deviation of 0.015?Å from the least-squares plane through all the non-H atoms. In the crystal, N-H?N hydrogen bonds link the mol-ecules into infinite C(4) chains running along [101].

SUBMITTER: Wang F

PROVIDER: S-EPMC3007560 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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5-Bromo-1H-thieno[2,3-d]imidazole.

Wang Fen F Ninkovic Sacha S Collins Michael M Moore Curtis C Rheingold Arnold L AL Yanovsky Alex A

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8

The crystal structure of the title compound, C(5)H(3)BrN(2)S, shows that bromination of 1H-thieno[2,3-d]imidazole with N-bromo-succinimide in acetonitrile occurs at position 5 of the bicyclic system. The mol-ecule is almost planar, with a mean deviation of 0.015 Å from the least-squares plane through all the non-H atoms. In the crystal, N-H⋯N hydrogen bonds link the mol-ecules into infinite C(4) chains running along [101]. ...[more]

PMID: 21588332

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